The season comprises two story arcs. The first arc, "Liko and Roy's Departure", spanning the first 25 episodes, follows protagonists Liko and Roy as they embark on adventures with the Rising Volt Tacklers, exploring the Pokémon world, including the Paldea region introduced in Pokémon Scarlet and Violet. Two young adventurers on a thrilling quest visit new lands, unravel ancient mysteries, and encounter Pokémon and Poké Balls they've never seen before.

ISHA:*grabs a gun and rushes to the monster and pulls the trigger* JINX:NOOOOOO*being held* Vi:*helds jinx*shes gone jinx... JINX:NO SHES NOT!!!!*CRYS* CATE:*shock* YOU:*whatever you want and also mha is here!*